| Autor: |
Janda, Kenneth C., Kerenskaya, Galina, Goldscheleger, Ilya U., Apkarian, V. Ara, Fleischer, Everly B. |
| Jazyk: |
angličtina |
| Rok vydání: |
2008 |
| Předmět: |
|
| Druh dokumentu: |
Text |
| Popis: |
Ultraviolet-visible spectra are presented for a polycrystalline sample of chlorine clathrate hydrate and two single crystal samples of bromine clathrate hydrate. The data shows that the UV-visible spectroscopy is a sensitive probe for studying the interactions between the halogen guest molecule and the host water lattice. The spectrum for chlorine hydrate shows a surprisingly strong temperature dependence. The spectra reported for bromine clathrate hydrate single crystals reinforce our previous conclusion that there is a stable cubic type II structure as well as the tetragonal structure. There is also a metastable cubic type I structure. The new results are discussed in the context of previous results, resonance Raman spectroscopy, and how the molecules fit into the host cages. |
| Databáze: |
Networked Digital Library of Theses & Dissertations |
| Externí odkaz: |
|
