Synthesis of Chiral N-Heterocyclic Carbene Precursors and Key Intermediates for Catalytic Enantioselective Cyclizations of Conjugated Trienes

Autor:	Wilkerson, Phillip D
Rok vydání:	2012
Předmět:	Asymmetric Catalysis Catalyst Design N-heterocyclic carbenes
Zdroj:	Chemistry Theses.
Druh dokumentu:	Text
Popis:	Cocatalyzed reactions using Brønsted acids and chiral N-heterocyclic carbenes to yield highly enantioselective products have been reported recently in many journals. The development of new chiral N-heterocyclic carbenes is a competitive field among synthetic chemist. In a recent study we found that conjugated trienes could be cyclized using Brønsted acids and chiral N-heterocyclic carbenes. The synthesis of novel chiral N-heterocyclic carbene precursors, and the precursors to novel conjugated trienes are reported herein.
Databáze:	Networked Digital Library of Theses & Dissertations
Externí odkaz:	http://digitalarchive.gsu.edu/chemistry_theses/49 http://digitalarchive.gsu.edu/cgi/viewcontent.cgi?article=1048&context=chemistry_theses Zobrazit plný text záznamu