Iron-Catalyzed Oxidative C−O and C−N Coupling Reactions Using Air as Sole Oxidant

Autor:	Purtsas, Alexander, Rosenkranz, Marco, Dmitrieva, Evgenia, Kataeva, Olga, Knölker, Hans-Joachim
Jazyk:	angličtina
Rok vydání:	2022
Předmět:	air C−H activation homogeneous catalysis iron oxidative amination Luft C-H-Aktivierung homogene Katalyse oxidative Eisenamination info:eu-repo/classification/ddc/540 ddc:540 info:eu-repo/classification/ddc/660 ddc:660
Druh dokumentu:	Článek
ISSN:	1521-3765
DOI:	10.1002/chem.202104292
Popis:	We describe the oxygenation of tertiary arylamines, and the amination of tertiary arylamines and phenols. The key step of these coupling reactions is an iron-catalyzed oxidative C−O or C−N bond formation which generally provides the corresponding products in high yields and with excellent regioselectivity. The transformations are accomplished using hexadecafluorophthalocyanine−iron(II) (FePcF16) as catalyst in the presence of an acid or a base additive and require only ambient air as sole oxidant.
Databáze:	Networked Digital Library of Theses & Dissertations
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