Autor: |
Purtsas, Alexander, Rosenkranz, Marco, Dmitrieva, Evgenia, Kataeva, Olga, Knölker, Hans-Joachim |
Jazyk: |
angličtina |
Rok vydání: |
2022 |
Předmět: |
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Druh dokumentu: |
Článek |
ISSN: |
1521-3765 |
DOI: |
10.1002/chem.202104292 |
Popis: |
We describe the oxygenation of tertiary arylamines, and the amination of tertiary arylamines and phenols. The key step of these coupling reactions is an iron-catalyzed oxidative C−O or C−N bond formation which generally provides the corresponding products in high yields and with excellent regioselectivity. The transformations are accomplished using hexadecafluorophthalocyanine−iron(II) (FePcF16) as catalyst in the presence of an acid or a base additive and require only ambient air as sole oxidant. |
Databáze: |
Networked Digital Library of Theses & Dissertations |
Externí odkaz: |
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