Temperature extension of NaCl Pitzer coefficients and ∆RG°(NaCl)

Autor: Voigt, Wolfgang
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Druh dokumentu: Článek
ISSN: 2751-0921
Popis: The general temperature range for THEREDA is currently limited to 0 to about 110°C. For the important electrolyte NaCl there are thermodynamic data available to 200°C and above. To cover this larger temperature range for the Pitzer coefficients, a refit of the temperature functions of Greenberg, J. P. and Møller, N. (Geochim. Cosmochim. Acta 53 (1989) 2503-2518) is presented. A corresponding function for the solubility constant of NaCl is deduced from IUPAC recommended data. The data set for NaCl, thus extended in its range of validity up to 200°C, is implemented in THEREDA.
Databáze: Networked Digital Library of Theses & Dissertations