Vibrational relaxation and dephasing of Rb2 attached to helium nanodroplets
Autor: | Grüner, Barbara, Schlesinger, Martin, Heister, Philipp, Strunz, Walter T., Stienkemeier, Frank, Mudrich, Marcel |
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Jazyk: | angličtina |
Rok vydání: | 2014 |
Předmět: |
info:eu-repo/classification/ddc/540
ddc:540 zweiatomige Rubidiummoleküle Spektroskopie Pump-Probe-Technik Raman-Streuung Helium Rubidium wave-packet dynamics resolved ionization spectroscopy pump-probe spectroscopy fractional revivals ultrafast dynamics condensed-phase solid kr energy relaxation raman-scattering he-4 clusters |
Zdroj: | Physical chemistry, chemical physics 2011;13:6816–6826, ISSN: 1463-9076 |
Druh dokumentu: | Článek |
DOI: | 10.1039/c0cp02355h |
Popis: | The vibrational wave-packet dynamics of diatomic rubidium molecules (Rb2) in triplet states formed on the surface of superfluid helium nanodroplets is investigated both experimentally and theoretically. Detailed comparison of experimental femtosecond pump–probe spectra with dissipative quantum dynamics simulations reveals that vibrational relaxation is the main source of dephasing. The rate constant for vibrational relaxation in the first excited triplet state 13Σ+g is found to be constant γ ≈ 0.5 ns−1 for the lowest vibrational levels v [less, similar] 15 and to increase sharply when exciting to higher energies. Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich. |
Databáze: | Networked Digital Library of Theses & Dissertations |
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