Bismuth(III) benzohydroxamates: powerful anti-bacterial activity against Helicobacter pylori and hydrolysis to a unique Bi34 oxido-cluster [Bi34O22(BHA)22(H-BHA)14(DMSO)6]

Autor:	Pathak, Amita, Blair, Victoria L., Ferrero, Richard L., Mehring, Michael, Andrews, Philip C.
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	info:eu-repo/classification/ddc/530 ddc:530 Bismut Carboxylate Cluster Helicobacter Pylori Bismut Carboxylate Cluster Helicobacter Pylori antibakterielle Materialien Technische Universität Chemnitz Allianzlizenz bismuth carboxylates cluster helicobacter pylori anti-bacterial materials
Zdroj:	Chemical Communications, 2014,50, 15232-15234
Druh dokumentu:	Článek
ISSN:	1359-7345
DOI:	10.1039/C4CC07329K
Popis:	Reaction of BiPh3 or Bi(OtBu)3 with benzohydroxamic acid (H2-BHA) results in formation of novel mono- and di-anionic hydroxamato complexes; [Bi2(BHA)3]∞1, [Bi(H-BHA)3] 2, [Bi(BHA)(H-BHA)] 3, all of which display nM activity against Helicobacter pylori. Subsequent dissolution of [Bi2(BHA)3]∞ in DMSO/toluene results in hydrolysis to the first structurally authenticated {Bi34} oxido-cluster [Bi34O22(BHA)22(H-BHA)14(DMSO)6] 4. Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
Databáze:	Networked Digital Library of Theses & Dissertations
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