A general route for the synthesis of hydrido-carboxylate complexes of the type MH(CO)(κ 3-OCOR)(PPh 3) 2 [M = Ru, Os; R = CH 3, CH 2Cl, C 6H 5, CH(CH 3) 2] and their use as precatalysts for hydrogenation and hydroformylation reactions

Autor: Rosales, Merlín, Alvarado, Beatriz, Arrieta, Federico, De La Cruz, Carlos, González, Ángel, Molina, Karely, Soto, Otto, Salazar, Yslamar
Zdroj: In Polyhedron 2008 27(2):530-536
Databáze: ScienceDirect