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This volume covers the synthesis of compounds containing a nitrogen functionality bonded to sp3-hybridized carbon atoms. However, only in the cases of nitroalkanes, nitrosoalkanes, azides, and N,N-dihaloamines are the substituents R1 and R2 strictly limited to alkyl groups. Aliphatic diazonium compounds are divided into the subclasses of short-lived alkanediazonium compounds and the less labile alkenediazonium compounds. 1,2-Dialkyldiazene 1-oxides and azoxy compounds carrying a vinyl group at one of the two different nitrogen atoms are also covered. In the cases of azo compounds and tetrazenes, derivatives bearing aryl, vinyl, or acyl substituents at the nitrogen functionality are described along with such compounds having only alkyl groups. |
