Molecular structure of Te2 Mg2(μ3-Cl2)(μ2-Cl4)Cl6(THF)4·CH2 Cl2

Autor: Hesse Malte, Beckmann Jens
Jazyk: angličtina
Rok vydání: 2014
Předmět:
Zdroj: Main Group Metal Chemistry, Vol 37, Iss 5-6, Pp 169-171 (2014)
Druh dokumentu: article
ISSN: 0792-1241
2191-0219
DOI: 10.1515/mgmc-2014-0024
Popis: A few crystals of the title compound Te2 Mg2(μ3-Cl2)(μ2-Cl4)Cl6(THF)4·CH2 Cl2 (1·CH2 Cl2) were isolated accidentally from a reaction mixture that contained the starting materials TeCl4 and t-BuMgCl in THF and that was recrystallized from CH2 Cl2. The molecular structure of 1·CH2 Cl2 determined by X-ray crystallography features a rare TeCl3- moiety.
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