Properties of Passive Films Formed on Ferrite-Martensite and Ferrite-Pearlite Steel Microstructures

Autor: Aytac Yilmaz, Can Ozkan, Jilt Sietsma, Yaiza Gonzalez-Garcia
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Metals, Vol 11, Iss 4, p 594 (2021)
Druh dokumentu: article
ISSN: 2075-4701
DOI: 10.3390/met11040594
Popis: The effect of ferrite-pearlite and ferrite-martensite phase combinations on the passive layer properties of low carbon steel is investigated in a 0.1 M NaOH solution. Heat treatments were designed to obtain ferrite-pearlite and ferrite-martensite microstructures with similar ferrite volume fractions. Potentiostatic polarisation and electrochemical impedance spectroscopy (EIS) results demonstrated the lower barrier properties of passive films on ferrite-martensite microstructure compared to the ones formed on ferrite-pearlite microstructure. This was attributed to the higher donor density of the passive layer on ferrite-martensite samples, measured with Mott–Schottky analysis. This behaviour was explained by the complex microstructure morphology of the martensite phase that led to the formation of a more defective passive film.
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