Pollutant Removal from Gaseous and Aqueous Phases using Hydrochar-based Activated Carbon

Autor: Monica Puccini, Eleonora Stefanelli, Luca Tasca Andrea, Sandra Vitolo
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Chemical Engineering Transactions, Vol 67 (2018)
Druh dokumentu: article
ISSN: 2283-9216
DOI: 10.3303/CET1867107
Popis: In this study, hydrochar (HC) produced at industrial scale by hydrothermal carbonization of municipal woody and herbaceous prunings was used for producing activated carbon by KOH chemical activation. Different KOH/HC ratios were studied to produce highly porous materials with high surface area. Activated carbon with a BET surface area up to 1739 m2/g was obtained for a 3:1 KOH/HC ratio. Adsorption properties of obtained samples were studied for removing pollutants both from gas and liquid phases. Thermogravimetric analyzer (TGA) was used for evaluating the removal capacities of CO2 from a gaseous phase, while UV-Vis spectroscopy was used for evaluating the removal capacities of an emerging contaminant from an aqueous phase. All samples showed a good CO2 adsorption capacity at 27 °C, reaching 84.5 mg CO2/g sorbent for hydrochar activated with an impregnation ratio of 2:1. Moreover, activated chars exhibited a high removal efficiency (up to 97.9 % for a 3:1 KOH/HC ratio) for atrazine, which is one of the most common pesticides detected in superficial and groundwater aquifers.
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