(μ2-2-Methoxyethanol-κ3O1:O1,O3)(2-methoxyethanol-κO1)tris(μ2-3,4,5,6-tetrafluoro-o-phenylene-κ2C1:C2)trimercury(II)
Autor: | Raúl Castañeda, Sergiu Draguta, Andrey Yakovenko, Marina Fonari, Tatiana Timofeeva |
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Jazyk: | angličtina |
Rok vydání: | 2014 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 5, Pp m164-m165 (2014) |
Druh dokumentu: | article |
ISSN: | 1600-5368 16005368 |
DOI: | 10.1107/S1600536814006898 |
Popis: | In the title compound, [Hg3(C6F4)3(C3H8O2)2], two O atoms from one 2-methoxyethanol ligand and one O atom from the second 2-methoxyethanol ligand coordinate three HgII atoms [Hg—O = 2.765 (7)–2.890 (8) Å] in the trimeric organomercurial Lewis acid (o-C6F4Hg)3. The hydroxy groups are involved in formation of intra- and intermolecular O—H...O hydrogen bonds; the latter link two molecules into centrosymmetric dimers. An extensive net of weak intermolecular C—H...F interactions further consolidates the crystal packing. |
Databáze: | Directory of Open Access Journals |
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