Preparation and curing process optimization of tert-butyl peroxy benzoate/acrylated epoxy soybean oil composites

Autor:	ZHAO Feng, LI Meng, ZHAO Xin, LI Zheng
Jazyk:	čínština
Rok vydání:	2023
Předmět:	tert-butyl peroxy benzoate acrylated epoxidized soybean oil composite reaction kinetics curing process Organic chemistry QD241-441 Chemical engineering TP155-156 Chemicals: Manufacture use etc. TP200-248
Zdroj:	Hecheng xiangjiao gongye, Vol 46, Iss 5, Pp 388-393 (2023)
Druh dokumentu:	article
ISSN:	1000-1255 02764423
DOI:	10.19908/j.cnki.ISSN1000-1255.2023.05.0388
Popis:	tert-butyl peroxy benzoate (TBPB)/acrylated epoxy soybean oil composite(AESO) composite was prepared by immersion compression for-ming technology, and its curing process and structure were investigated. The results showed that the reaction activation energy of TBPB/AESO composite calculated based on Kissinger method and Starink method was 78.803 kJ/mol. Sesthk-Berggren was selected as the curing model, and the calculated curing kinetics equation based on the Malek method fitted well with the experimental data. The optimized curing process of TBPB/AESO involved increasing slowly the temperature to 407 K, then increasing rapidly the temperature to 424 K for constant temperature curing, and finally increasing slowly the temperature to 489 K for a certain period of time.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/cfd7456c0276442398d4cdee4dcae3c0 Zobrazit plný text záznamu View record in DOAJ