Chromoselective access to Z- or E- allylated amines and heterocycles by a photocatalytic allylation reaction

Autor: Ana María Martínez-Gualda, Rafael Cano, Leyre Marzo, Raúl Pérez-Ruiz, Javier Luis-Barrera, Rubén Mas-Ballesté, Alberto Fraile, Víctor A. de la Peña O’Shea, José Alemán
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Nature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-019-10441-4
Popis: Tsuji–Trost allylation is a traditional method for selective C-C bond formation that involves the use of palladium-based catalysts. Here, the authors report a metal-free, photocatalytic allylation of several heterocycles, amines and alcohols, which can be easily tuned towards the Z- or E- allylated product.
Databáze: Directory of Open Access Journals