| Autor: |
Mikhail N. Simonov, Vladimir A. Rogov, Marina Yu. Smirnova, Vladislav A. Sadykov |
| Jazyk: |
angličtina |
| Rok vydání: |
2017 |
| Předmět: |
|
| Zdroj: |
Catalysts, Vol 7, Iss 9, p 268 (2017) |
| Druh dokumentu: |
article |
| ISSN: |
2073-4344 |
| DOI: |
10.3390/catal7090268 |
| Popis: |
For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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