The kinetics of the reaction of 6-substituted nicotinic acids and some p-substituted benzoic acids with diazodiphenylmethane in various alcohols

Autor: MILICA M. MISIC-VUKOVIC, BRATISLAV Z. JOVANOVIC, SASA Z. DRMANIC
Jazyk: angličtina
Rok vydání: 2000
Předmět:
Zdroj: Journal of the Serbian Chemical Society, Vol 65, Iss 7, Pp 481-490 (2000)
Druh dokumentu: article
ISSN: 0352-5139
Popis: Rate constants have been determined for the reactions of diazodiphenylmethane with a number of 6-substituted nicotinic acids and p-substituted benzoic acids in twelve alcohols. A comparative study was used to evaluate and compare the Hammett r values and solvent effects. Multiple correlations of the log k values for the reactions of 6-substituted nicotinic acids and p-substituted benzoic acids in 12 alcohols with groups of suitable solvent parameters are very successful. The transmission of electronic effects through the pyridine ring system in compared with that in benzene.
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