Poly[[bis[3-(1H-tetrazol-1-yl)propanoic acid-κN4]cadmium]-di-μ-thiocyanato-κ2N:S;κ2S:N]

Autor: Xiang Liu, Zhong-Xing Su, Yuan Zhang, Jian-Guo Wang
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 68, Iss 5, Pp m593-m594 (2012)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536812014730
Popis: In the title compound, [Cd(NCS)2(C4H6N4O2)2]n, the CdII cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN− anions and two N atoms from two 3-(1H-tetrazol-1-yl)propanoic acid (Htzp) ligands in a distorted octahedral geometry. The SCN− anions bridge the CdII cations into a layer structure parallel to (100). A weak intramolecular C—H...N interaction occurs. The layers are further assembled into a three-dimensional supramolecular structure via classical O—H...O hydrogen bonds.
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