Spectroscopic characterization of two peroxyl radicals during the O2-oxidation of the methylthio radical

Autor: Zhuang Wu, Xin Shao, Bifeng Zhu, Lina Wang, Bo Lu, Tarek Trabelsi, Joseph S. Francisco, Xiaoqing Zeng
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Communications Chemistry, Vol 5, Iss 1, Pp 1-8 (2022)
Druh dokumentu: article
ISSN: 2399-3669
DOI: 10.1038/s42004-022-00637-z
Popis: The atmospheric oxidation of dimethyl sulfide affects the Earth’s climate, but the intricate pathways of this complex reaction are still not fully described. Here, the authors use an optimized flash pyrolysis method for gas-phase generation of the methylthio radical to study its O2-oxidation via matrix-isolation spectroscopy, and unambiguously identify two peroxyl radical intermediates.
Databáze: Directory of Open Access Journals
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