Synthesis and X-ray Diffraction of Cyclopalladated Compounds Derived from Imine Ligands
| Autor: | Basma Al Janabi, Juan M. Ortigueira, Jose Manuel Vila |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Chemistry Proceedings, Vol 12, Iss 1, p 52 (2022) |
| Druh dokumentu: | article |
| ISSN: | 2673-4583 |
| DOI: | 10.3390/ecsoc-26-13699 |
| Popis: | The crystal structures of mononuclear cyclopalladated compounds with phosphine ligands are investigated. The reactions of the five-membered cyclopalladated dinuclear complexes [Pd(L)(µ-Cl)]2 with the monophosphine ligand (PPh3) and diphosphine ligand (dppm) in the molar ratio of 1:2, and ammonium hexafluoride in the case of compound b, result in the mononuclear complexes [Pd{2,3,4-(CHO)C6H3C(H)=NCy}{PPh3}[Cl] (1a) and [Pd{2,3,4-(CHO)C6H3C(H)=NCy}{Ph2PCH2PPh2-P,P}][PF6] (1b). |
| Databáze: | Directory of Open Access Journals |
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