Popis: |
Acid rock drainage (ARD) is one of the most serious and potentially lasting environmental issues for the mining industry. Many researchers investigated the impact of ARD on downstream farmland, but few focused on the soil properties change around waste rock heaps. In this study, a total of 119 soil samples were taken around the 35 waste rock heaps which are scattered in 12 mining sites in an abandoned pyrite mining area (Baihe County, Northwest China). Both rainy and dry seasons of ARD were collected from the discharge outlet of each mining site. The bulk levels of potentially toxic elements (PTEs), including As, Cd, Cu, Ni, Cr, Zn, Pb, Fe, Mn, and F, in waste rock, soil, and ARD samples were analyzed. Leaching concentration and chemical speciation of these PTEs in soils were further investigated. The results show that the ARD had very high pollution loads of PTEs both in the rainy season and dry season, continuously exporting pollutants to the surrounding soils. More than 70% of the soil samples were acidic (pH |