| Autor: |
Dr. Muhammad Usman, An‐Chih Yang, Dr. Arif I. Inamdar, Dr. Saqib Kamal, Ji‐Chiang Hsu, Prof. Dun‐Yen Kang, Prof. Tien‐Wen Tseng, Prof. Chen‐Hsiung Hung, Prof. Kuang‐Lieh Lu |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
ChemistryOpen, Vol 11, Iss 2, Pp n/a-n/a (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2191-1363 |
| DOI: |
10.1002/open.202100295 |
| Popis: |
Abstract Integration of metal‐organic frameworks (MOFs) as components of advanced electronic devices is at a very early phase of development and the fundamental issues related to their crystal growth on conductive substrate need to be addressed. Herein, we report on the structural characterization of a newly synthesized Sr‐based MOF {[Sr(2,5‐Pzdc)(H2O)2] ⋅ 3 H2O}n (1) and the uniform crystal growth of compound 1 on a conducting glass (fluorine doped tin oxide (FTO)) substrate using electrochemical deposition techniques. The Sr‐based MOF 1 was synthesized by the reaction of Sr(NO3)2 with 2,5‐pyrazinedicarboxylic acid dihydrate (2,5‐Pzdc) under solvothermal conditions. A single‐crystal X‐ray diffraction analysis revealed that 1 has a 3D structure and crystallizes in the triclinic P1‾ space group. In addition, the uniform crystal growth of this MOF on a conducting glass (FTO) substrate was successfully achieved using electrochemical deposition techniques. Only a handful of MOFs have been reposed to grown on conductive surfaces, which makes this study an important focal point for future research on the applications of MOF‐based devices in microelectronics. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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