Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)
| Autor: | Edwin Weber, Florian O. R. L. Mertens, Tony Böhle, Frank Eissmann |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 3, Pp m279-m279 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053681000454X |
| Popis: | The asymmetric unit of the title complex, [Co(DMF)6](ClO4)2 (DMF = N,N-dimethylformamide, C3H7NO), consists of two half complex cations with the Co2+ metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co2+ ion is coordinated by six molecules of DMF in a slightly distorted octahedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C—H...O hydrogen-bonding interactions. |
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