Poly[[(μ-1H-benzimidazole-5,6-dicarboxylato)zinc(II)] monohydrate]

Autor: Zhao-yang Li, Jing-wei Dai, Shan-tang Yue
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 7, Pp m775-m775 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809022107
Popis: The three-dimensional polymeric title compound, {[Zn(C9H4N2O4)]·H2O}n, contains one crystallographically independent ZnII atom, one fully deprotonated 1H-benzimidazole-5,6-dicarboxylate (bdc) ligand and one uncoordinated water molecule. The ZnII atom is four-coordinated by three O atoms and one N atom from the bdc ligands, giving a distorted tetrahedral coordination geometry. The uncoordinated water molecule is bound to the main structure through a strong bdc–water N—H...O hydrogen bond, and two much weaker water–bdc O—H...O interactions.
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