| Autor: |
Zhi-Yan Wu, Ting Chen, Min Huang, Zi-Ang Nan, Jin-Sheng Liao, Zhu Zhuo, You-Gui Huang |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Results in Chemistry, Vol 5, Iss , Pp 100958- (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2211-7156 |
| DOI: |
10.1016/j.rechem.2023.100958 |
| Popis: |
A rhombic metallocycle [CoII6Cl6(L)2(HL)2]·5.5DMF·3.5H2O (1) (H2L = tris(2-naphthimidazolylmethyl) amine) composed of two CoIICl(HL) moieties and two CoIICl(L) moieties alternately bridged by two μ3-CoII ions has been synthesized under solvothermal condition. Each metallocycle associate with its six neighbors through intermolecular π···π interactions between naphthimidazolylmethyl arms forming a supramolecular framework with a pcu network. Magnetic measurements on the metallocycle reveal dominant antiferromagnetic couplings between CoII centers. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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