Salts of 4-[(benzylamino)carbonyl]-1-methylpyridinium and iodide anions with different cation:iodine stoichiometric ratios
| Autor: | Vitalii V. Rudiuk, Anna M. Shaposhnyk, Vyacheslav M. Baumer, Igor A. Levandovskiy, Svitlana V. Shishkina |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 12, Pp 1219-1223 (2021) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989021011300 |
| Popis: | The two iodide salts, 4-[(benzylamino)carbonyl]-1-methylpyridinium iodide–iodine (2/1), C14H15N2O+·I−·0.5I2, I, and 4-[(benzylamino)carbonyl]-1-methylpyridinium triiodide, C14H15N2O+·I3−, II, with different cation:iodine atoms ratios were studied. Salt I contains one cation, one iodide anion and half of the neutral I2 molecule in the asymmetric unit (cation:iodine atoms ratio is 1:2). Salt II contains two cations, one triiodide anion (I3−) and two half triiodide anions (cation:iodine atoms ratio is 1:3). The NH group forms N—H...I hydrogen bonds with the I− anion in the crystal of I or N—H...O hydrogen bonds in II where only triiodide anions are present. |
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