The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate

Autor: MILICA M. MISIC-VUKOVIC, SLOBODAN D. PETROVIC, MLADJEN L. MICEVIC
Jazyk: angličtina
Rok vydání: 2000
Předmět:
Zdroj: Journal of the Serbian Chemical Society, Vol 65, Iss 12, Pp 857-866 (2000)
Druh dokumentu: article
ISSN: 0352-5139
Popis: The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data.
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