Bis(1H-imidazole-κN3)bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II)
| Autor: | Sheng-Liang Ni, Ming-Xing Zhao, Hai-Xia Ge |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 8, Pp m1123-m1124 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053681102839X |
| Popis: | The structure of the title compound, [Cu(C8H7O2)2(C3H4N2)2(C8H8O2)2], consists of centrosymmetric monomeric units, in which the CuII atom has a tetragonally distorted octahedral coordination involving two imidazole N atoms and two carboxylate O atoms in the square plane [Cu—N = 1.964 (3) and Cu—O = 1.960 (2) Å] and 2-methylbenzoic acid O atoms in axial sites [Cu—O = 2.753 (3) Å]. Within the complex, the carboxylic acid forms intramolecular O—H...O hydrogen bonds, while the molecules are assembled through N—H...O(carboxyl) hydrogen bonds into chains extending along the a-axis direction. These chains are further linked by weak π–π interactions [centroid–centroid separation = 3.930 (2) Å]. |
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