| Autor: |
Zhongkai Li, Mariolino Carta, Neil B. McKeown, Raphael E. Agbenyeke, Jean‐Charles Eloi, David J. Fermin, Omotayo A. Arotiba, Frank Marken |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
ChemElectroChem, Vol 11, Iss 9, Pp n/a-n/a (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2196-0216 |
| DOI: |
10.1002/celc.202300807 |
| Popis: |
Abstract Ionic diodes are components in ionic circuits for AC‐electricity driven desalination and ion extraction processes. Independent of the ionic diode type/mechanism, achieving ionic current rectification at high ionic strengths is challenging but important, for example in seawater desalination and treatment of brine. Here, the butylation of a molecularly rigid (glassy) polymer of intrinsic microporosity (PIM‐EA‐TB) is shown to give anionic diodes with ultrahigh rectification effects (associated with interfacial resistivity) even in high ionic strength aqueous 2 M NaCl solution. The effect is rationalised based on polymer structure affecting ion transport. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
Plný text