Design and application of a novel and effective ligand for the Cu-catalyzed amination of aryl halides in water
| Autor: | Lifang Wang, Xinhai Zhu, Zexuan Liang, Manna Huang, Yiqian Wan |
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| Jazyk: | angličtina |
| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Green Chemistry Letters and Reviews, Vol 16, Iss 1 (2023) |
| Druh dokumentu: | article |
| ISSN: | 17518253 1751-7192 1751-8253 |
| DOI: | 10.1080/17518253.2022.2147027 |
| Popis: | ABSTRACTAn effective ligand for the Ullmann-type C–N coupling reaction in water has been obtained using a novel tactic, namely, introducing a third group into the ligand to both improve the ligand’s water solubility and enhance the ligand’s coordinating ability. Applying this method, we have developed an effective ligand for the Cu-catalyzed amination of aryl halides, in particular, for aryl chlorides in water. The substrate diversity of the catalyst system, relatively less time required (6–12 h), and water as the reaction solvent make it attractive in both academia and industry. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
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