Metal–organic frameworks and their derivatives for optimizing lithium metal anodes

Autor: Zhaoyang Wang, Zijuan Du, Yiyang Liu, Caroline E. Knapp, Yuhang Dai, Jianwei Li, Wei Zhang, Ruwei Chen, Fei Guo, Wei Zong, Xuan Gao, Jiexin Zhu, Chuanliang Wei, Guanjie He
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: eScience, Vol 4, Iss 4, Pp 100189- (2024)
Druh dokumentu: article
ISSN: 2667-1417
DOI: 10.1016/j.esci.2023.100189
Popis: Lithium metal anodes (LMAs) have been considered the ultimate anode materials for next-generation batteries. However, the uncontrollable lithium dendrite growth and huge volume expansion that can occur during charge and discharge seriously hinder the practical application of LMAs. Metal–organic framework (MOF) materials, which possess the merits of huge specific surface area, excellent porosity, and flexible composition/structure tunability, have demonstrated great potential for resolving both of these issues. This article first explores the mechanism of lithium dendrite formation as described by four influential models. Subsequently, based on an in-depth understanding of these models, we propose potential strategies for utilizing MOFs and their derivatives to suppress lithium dendrite growth. We then provide a comprehensive review of research progress with respect to various applications of MOFs and their derivatives to suppress lithium dendrites and inhibit volume expansion. The paper closes with a discussion of perspectives on future modifications of MOFs and their derivatives to achieve stable and dendrite-free lithium metal batteries.
Databáze: Directory of Open Access Journals