Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands
| Autor: | Saeideh Hosseini, Farzin Marandi, Ertan Şahin, Seyid Javad Musevi |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Journal of Chemistry, Vol 2013 (2013) |
| Druh dokumentu: | article |
| ISSN: | 2090-9063 2090-9071 |
| DOI: | 10.1155/2013/159125 |
| Popis: | A new Pb(II) complex, [Pb(bp)2(btfa)2] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically “inactive” electron lone pair with holodirected coordination spheres. In solid state, there are π⋯π, C–H⋯F, C–H⋯O, and F⋯F interactions between adjacent units to generate 3D supramolecular structure. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|