Studies on the Hall-Heroult aluminum electrowinning process

Autor: Prasad Shiva
Jazyk: angličtina
Rok vydání: 2000
Předmět:
Zdroj: Journal of the Brazilian Chemical Society, Vol 11, Iss 3, Pp 245-251 (2000)
Druh dokumentu: article
ISSN: 0103-5053
Popis: Studies on the electrolysis of cryolite-alumina melt showed that even the best equipped smelter, functioning at 960 ºC, has only 33% energy efficiency. For stable functioning of the smelter at 3% alumina the minimum wt% ratio NaF/AlF3 was found to be 1.11. The anodes located on down-stream row were found to face more turbulence; raising their level by 4 cm resulted in decreasing the number of burnoffs. A careful selection of potlining material improved the pot life. The stability of the aluminum-bath interface is one of the major factors affecting the current efficiency. An improved cell design has been proposed to achieve the ultimate aluminum-bath interface stability. The proposed cell design should allow a reduction of the cathode-to-anode distance producing a lower voltage and improving the power efficiency.
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