Catalytic Performance of a Magnetic Core-Shell Iron(II) C-Scorpionate under Unconventional Oxidation Conditions
| Autor: | Inês A. S. Matias, Ana P. C. Ribeiro, Ana M. Ferraria, Ana M. Botelho do Rego, Luísa M. D. R. S. Martins |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | Nanomaterials, Vol 10, Iss 11, p 2111 (2020) |
| Druh dokumentu: | article |
| ISSN: | 10112111 2079-4991 |
| DOI: | 10.3390/nano10112111 |
| Popis: | For the first time, herein is reported the use of a magnetic core-shell support for a C-scorpionate metallic complex. The prepared hybrid material, that consists on the C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz, pyrazolyl) immobilized at magnetic core-shell particles (Fe3O4/TiO2), was tested as catalyst for the oxidation of secondary alcohols using the model substrate 1-phenylethanol. Moreover, the application of alternative energy sources (e.g., ultrasounds, microwaves, mechanical or thermal) for the peroxidative alcohol oxidation using the magnetic heterogenized iron(II) scorpionate led to different/unusual outcomes that are presented and discussed. |
| Databáze: | Directory of Open Access Journals |
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