Rubidium pentaaqua(l-serine)cobalt(II) hexahydrogenhexamolybdocobaltate(III) l-serine monosolvate decahydrate
Autor: | Jun Iijima, Haruo Naruke, Hiroshi Takiyama |
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Jazyk: | angličtina |
Rok vydání: | 2013 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 11, Pp m612-m613 (2013) |
Druh dokumentu: | article |
ISSN: | 16005368 1600-5368 |
DOI: | 10.1107/S1600536813028304 |
Popis: | The Co2+ ion in the title compound, Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O, is coordinated by five water molecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb+ ion is irregularly coordinated by nine O atoms. In the crystal, the [H6CoIIIMo6O24]3− polyanions are stacked along the b-axis direction, mediated by bridging Rb—O bonds. N—H...O and O—H...O hydrogen bonds are observed involving the l-serine molecules. |
Databáze: | Directory of Open Access Journals |
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