Crystal structure of (Z)-4-methylbenzyl 3-[1-(5-methylpyridin-2-yl)ethylidene]dithiocarbazate
Autor: | Thahira Begum S. A. Ravoof, Edward R. T. Tiekink, Siti Aminah Omar, Sharifa Zaithun Begum, Mohamed I. M. Tahir |
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Jazyk: | angličtina |
Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 12, Pp o1071-o1072 (2015) |
Druh dokumentu: | article |
ISSN: | 2056-9890 20569890 |
DOI: | 10.1107/S205698901502407X |
Popis: | In the title dithiocarbazate compound, C17H19N3S2, the central CN2S2 residue is essentially planar (r.m.s. deviation = 0.0288 Å) and forms dihedral angles of 9.77 (8) and 77.47 (7)° with the substituted-pyridyl and p-tolyl rings, respectively, indicating a highly twisted molecule; the dihedral angle between the rings is 85.56 (8)°. The configuration about the C=N bond is Z, which allows for the formation of an intramolecular N—H...N(pyridyl) hydrogen bond. The packing features tolyl-methyl-C—H...N(imine), pyridyl-C—H...π(tolyl) and π–π interactions [between pyridyl rings with a distance = 3.7946 (13) Å], which generates jagged supramolecular layers that stack along the b axis with no directional interactions between them. |
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