Ni/NiFe2 dual-layer coating for SOFC steel interconnects application

Autor: Qingqing Zhao, Shujiang Geng, Xingye Gao, Gang Chen, Fuhui Wang
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Journal of Power Sources Advances, Vol 2, Iss , Pp 100011- (2020)
Druh dokumentu: article
ISSN: 2666-2485
DOI: 10.1016/j.powera.2020.100011
Popis: Ni/NiFe2 dual-layer coating is fabricated on SUS 430 stainless steel by magnetron sputtering for solid oxide fuel cells (SOFCs) interconnect application. Ni/NiFe2 coated steels are exposed to air at 800 °C for duration of up to 10 weeks in comparison with NiFe2 coated steels. Ni/NiFe2 coating is thermally converted to an oxide structure with an inner NiO layer and an outer NiFe2O4 spinel layer. NiO/NiFe2O4 oxide layer is more effective in blocking Cr migration and reducing oxidation rate during long-term exposure than a single NiFe2O4 layer converted from NiFe2 coating. Enhancements on oxidation resistance and Cr-blocking capability are attributed to NiO layer serving as a diffusion barrier between Cr2O3 and NiFe2O4.
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