Solar-Energy-Driven Cu-ZnO/TiO2 Nanocomposite Photocatalyst for the Rapid Degradation of Congo Red Azo Dye

Autor: Vividha Kondba Landge, Chao-Ming Huang, Vikas Sadashiv Hakke, Shirish Hari Sonawane, Sivakumar Manickam, Ming-Chun Hsieh
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Catalysts, Vol 12, Iss 6, p 605 (2022)
Druh dokumentu: article
ISSN: 2073-4344
DOI: 10.3390/catal12060605
Popis: This study effectively demonstrates the sonochemical synthesis of visible-light-responsive Cu-ZnO/TiO2 ternary Z-scheme heterojunction nanocomposite photocatalyst. The as-prepared photocatalyst was comprehensively characterized by techniques including high-resolution transmission electron microscopy (HRTEM), field emission scanning electron microscopy (FE-SEM) with energy dispersive X-ray analysis (EDX) and elemental dot mapping, X-ray diffraction (XRD), UV-Vis-diffuse reflectance spectroscopy (UV-Vis-DRS), Brunauer–Emmett–Teller (BET) surface area, and Fourier-transform infrared spectroscopy (FTIR). The photocatalytic activity of the Cu-ZnO/TiO2 nanocomposite photocatalyst was assessed for the degradation of Congo red (CR), an azo dye, under direct sunlight. The pseudo-first-order rate constant for CR degradation was found to be 0.09 min−1. The outcome implies that the synthesised nanocomposite photocatalyst demonstrates excellent photocatalytic activity under direct sunlight as 98% degradation of CR dye was achieved in approximately 20 min using the Cu-ZnO/TiO2 nanocomposite photocatalyst. Furthermore, its high recoverability and reusability of five times indicate its excellent catalytic potential.
Databáze: Directory of Open Access Journals
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