| Autor: |
Paolo Personnettaz, Steffen Landgraf, Michael Nimtz, Norbert Weber, Tom Weier |
| Jazyk: |
angličtina |
| Rok vydání: |
2019 |
| Předmět: |
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| Zdroj: |
Electrochemistry Communications, Vol 105, Iss , Pp - (2019) |
| Druh dokumentu: |
article |
| ISSN: |
1388-2481 |
| DOI: |
10.1016/j.elecom.2019.106496 |
| Popis: |
Mass and charge transport in liquid metal batteries are closely intertwined because of the fully liquid interior of the cells. We found that charging and discharging cycles may show pronounced asymmetries. They are caused by the presence (charge) or absence (discharge) of solutal convection. While the direction of thermal gradients in the positive electrode of a liquid metal battery depends on boundary conditions and thermodynamics in a non-trivial manner, the solutal gradient predictably changes direction from charge to discharge. The unstable density distribution during charge drives a flow strong enough to prevent any concentration polarization. In contrast, during discharge, the stable density gradient suppresses convection and leads to a substantial mass transport overvoltage. We illustrate this scenario by experimental data, numerical simulations and a physical model. Keywords: Electrorefining, Liquid electrode, Liquid metal batteries, Mass transport, Overvoltage, Solutal convection |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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Full Text from ScienceDirect