Crystal structure and Hirshfeld surface analysis of one-dimensional copper(II) coordination polymer incorporating succinate and tetramethylethylenediamine ligands
| Autor: | Adnan M. Qadir, Sevgi Kansiz, Necmi Dege, Georgina M. Rosair, Turganbay S. Iskenderov |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 7, Pp 1038-1041 (2020) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989020007227 |
| Popis: | The reaction of copper nitrate with succinic acid (succH) and N,N,N′,N′-tetramethylethylenediamine (TMEDA) in basic solution produces the complex catena-poly[[[(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)copper(II)]-μ-succinato-κ2O1:O4] tetrahydrate], {[Cu(C4H4O4)(C6H16N2)]·4H2O}n or {[Cu(succ)(tmeda)]·4H2O}n. Each carboxylate group of the succinate ligand coordinates to a CuII atom in a monodentate fashion, giving rise to a distorted square-planar geometry. The succinate ligands bridge the CuII centres, forming one-dimensional polymeric chains. Hydrogen bonds between the ligands and water molecules link these chains into sheets that lie parallel to the ac plane. Hirshfeld surface analysis, dnorm and two-dimensional fingerprint plots were examined to verify the contributions of the different intermolecular contacts within the supramolecular structure. |
| Databáze: | Directory of Open Access Journals |
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