8,13,26-Trioxa-23-thia-21-azapentacyclo[18.6.0.02,7.014,19.021,25]hexacosa-2(7),3,5,14,16,18-hexaene
| Autor: | Seenivasan Karthiga Devi, Thothadri Srinivasan, Santhanagopalan Purushothaman, Raghavachary Raghunathan, Devadasan Velmurugan |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 6, Pp o892-o892 (2013) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536813012804 |
| Popis: | In the title compound, C21H23NO3S, both the thiazole and oxazolidine rings adopt twist conformations. The mean plane of the thiazole ring makes a dihedral angle of 61.02 (7)° with the oxazolidine ring mean plane, and dihedral angles of 22.72 (6) and 75.07 (6)° with the benzene rings. The benzene rings are almost perpendicular to one another, making a dihedral angle of 89.14 (6)°. There are bifurcated intramolecular C—H...O hydrogen bonds in the molecular structure. In the crystal, molecules are linked via C—H...π interactions, forming chains propagating along [100]. |
| Databáze: | Directory of Open Access Journals |
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