Synthesis and assembly of extended quintulene

Autor: Hao Hou, Xin-Jing Zhao, Chun Tang, Yang-Yang Ju, Ze-Ying Deng, Xin-Rong Wang, Liu-Bin Feng, Dong-Hai Lin, Xu Hou, Akimitsu Narita, Klaus Müllen, Yuan-Zhi Tan
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-020-17691-7
Popis: Quintulene, a quintuple non-graphitic cycloarene, is challenging to synthesize. Here, the authors synthesize and characterize the cone-shaped extended quintulene and its bilayer dimer, and disclose its dimerization as an entropy-driven, second-order reaction with a substantial activation energy.
Databáze: Directory of Open Access Journals