1,1,2,2,2,3,3,3-Octacarbonyl-1,1,2,3-tetrakis(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane-κP)-triangulo-triosmium(0)
| Autor: | David M. Marolf, Kristen L. Brehm, Vincent M. Lynch, Gregory L. Powell |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 5, Iss 7, p x200935 (2020) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314620009359 |
| Popis: | The title compound, [Os3(C6H12N3P)4(CO)8], crystallizes in the orthorhombic space group Pbca with Z = 8. The molecule consists of a triangular triosmium(0) core surrounded by eight carbonyl ligands and four 1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane (or PTA) ligands. One Os atom is coordinated by two PTA ligands and two CO ligands, while the other two Os atoms are each bonded to a single PTA ligand and three CO ligands. There is a small disorder associated with the Os3 unit so that a minor orientation has an occupancy of 2.17 (4)%. The title compound represents the first structurally characterized triangular Os3 carbonyl cluster with four monodentate tertiary phosphane ligands. |
| Databáze: | Directory of Open Access Journals |
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