| Autor: |
Ee Teng Kho, Salina Jantarang, Zhaoke Zheng, Jason Scott, Rose Amal |
| Jazyk: |
angličtina |
| Rok vydání: |
2017 |
| Předmět: |
|
| Zdroj: |
Engineering, Vol 3, Iss 3, Pp 393-401 (2017) |
| Druh dokumentu: |
article |
| ISSN: |
2095-8099 |
| DOI: |
10.1016/J.ENG.2017.03.016 |
| Popis: |
Solar-powered carbon dioxide (CO2)-to-fuel conversion presents itself as an ideal solution for both CO2 mitigation and the rapidly growing world energy demand. In this work, the heating effect of light irradiation onto a bed of supported nickel (Ni) catalyst was utilized to facilitate CO2 conversion. Ceria (CeO2)-titania (TiO2) oxide supports of different compositions were employed and their effects on photothermal CO2 conversion examined. Two factors are shown to be crucial for instigating photothermal CO2 methanation activity: ① Fine nickel deposits are required for both higher active catalyst area and greater light absorption capacity for the initial heating of the catalyst bed; and ② the presence of defect sites on the support are necessary to promote adsorption of CO2 for its subsequent activation. Titania inclusion within the support plays a crucial role in maintaining the oxygen vacancy defect sites on the (titanium-doped) cerium oxide. The combination of elevated light absorption and stabilized reduced states for CO2 adsorption subsequently invokes effective photothermal CO2 methanation when the ceria and titania are blended in the ideal ratio(s). |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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