| Autor: |
Atsushi Kaga, Xiangyang Wu, Joel Yi Jie Lim, Hirohito Hayashi, Yunpeng Lu, Edwin K. L. Yeow, Shunsuke Chiba |
| Jazyk: |
angličtina |
| Rok vydání: |
2018 |
| Předmět: |
|
| Zdroj: |
Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 3047-3058 (2018) |
| Druh dokumentu: |
article |
| ISSN: |
1860-5397 |
| DOI: |
10.3762/bjoc.14.283 |
| Popis: |
The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF3)ppy}2(dtbbpy)](PF6) under blue LED light irradiation. Detailed mechanistic investigations through kinetics and photophysical studies revealed that the process operates under a radical chain mechanism, which is initiated through triplet-sensitization of xanthates by the long-lived triplet state of the iridium-based photocatalyst. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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