Poly[bis(μ3-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)]
| Autor: | Hai-Dong Wang, Min-Min Li, Hong-Yin He, Fu-Bin Jiang |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 4, Pp m416-m416 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809009052 |
| Popis: | The title complex, [Mn2(C8H3NO6)2(C12H8N2)2]n, was synthesized under hydrothermal conditions. The structure contains two independent MnII atoms, each coordinated in a distorted octahedral MnN2O4 geometry. [Mn2(phen)2] units (phen = 1,10-phenantroline) are bridged by 5-nitroisophthalate (nip) ligands into ladder-like chains parallel to [100]. Adjacent polymeric chains are linked by C—H...O and π–π interactions [centroid-to-centroid distance = 3.6369 (12) Å] into a two-dimensional framework parallel to (010). |
| Databáze: | Directory of Open Access Journals |
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