| Autor: |
Hamzah Fansuri, Warih Supriadi, Ratna Ediati, Wahyu Prasetyo Utomo, Ririn Eva Hidayati, Rendy Muhamad Iqbal, Dety Oktavia Sulistiono, Mohd Mustafa Al Bakri Abdullah, Subaer |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
Environmental Advances, Vol 15, Iss , Pp 100510- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2666-7657 |
| DOI: |
10.1016/j.envadv.2024.100510 |
| Popis: |
The immobilization of heavy metal ions in geopolymers is a promising solution to prevent environmental contamination. However, under acidic conditions, these ions can leach out. Our study focused on immobilizing Cd2+ and Pb2+ in fly ash-based geopolymers, assessing their effects on properties, and examining leaching kinetics at pH 5. We tested various ion concentrations (ranging from 1000 to 16000 ppm). Notably, the addition of 1000 ppm of Cd2+ and 4000 ppm of Pb2+ substantially improved compressive strength (24.28 and 35.56 MPa, respectively). Higher ion concentrations resulted in increased leaching. Post-leaching, we observed pore enlargement and surface cracks, indicating ion migration. The Shrinking Core Model best describes the leaching process, with diffusion being the primary mechanism, featuring reaction orders of 2.46 and 2.39 for Cd2+ and Pb2+, respectively. The model is suitable for predicting the release of immobilized heavy metal ions into the surrounding acidic environment. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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