| Autor: |
Hailong Xiong, Ruicheng Qian, Zhilin Liu, Rui Zhang, Ge Sun, Bingkun Guo, Fei Du, Shuyan Song, Zhen‐An Qiao, Sheng Dai |
| Jazyk: |
angličtina |
| Rok vydání: |
2021 |
| Předmět: |
|
| Zdroj: |
Advanced Science, Vol 8, Iss 11, Pp n/a-n/a (2021) |
| Druh dokumentu: |
article |
| ISSN: |
2198-3844 |
| DOI: |
10.1002/advs.202004943 |
| Popis: |
Abstract A general polymer‐assisted spinodal decomposition strategy is used to prepare hierarchically porous sodium super ionic conductor (NASICON)‐structured polyanion‐type materials (e.g., Na3V2(PO4)3, Li3V2(PO4)3, K3V2(PO4)3, Na4MnV(PO4)3, and Na2TiV(PO4)3) in a tetrahydrofuran/ethanol/H2O synthesis system. Depending on the boiling point of solvents, the selective evaporation of the solvents induces both macrophase separation via spinodal decomposition and mesophase separation via self‐assembly of inorganic precursors and amphiphilic block copolymers, leading to the formation of hierarchically porous structures. The resulting hierarchically porous Na3V2(PO4)3 possessing large specific surface area (≈77 m2 g−1) and pore volume (≈0.272 cm3 g−1) shows a high specific capacity of 117.6 mAh g−1 at 0.1 C achieving the theoretical value and a long cycling life with 77% capacity retention over 1000 cycles at 5 C. This method presented here can open a facile avenue to synthesize other hierarchically porous polyanion‐type materials. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
|
Nepřihlášeným uživatelům se plný text nezobrazuje |
K zobrazení výsledku je třeba se přihlásit.
|
