Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate

Autor: Xing Li, Tian-Hua Li, Mei-Qin Zha, Yue Bing, Wei-Wei Li
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 67, Iss 10, Pp m1464-m1465 (2011)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536811039341
Popis: In the centrosymmetric dinuclear title complex, [Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]·2H2O, the MnII cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenylquinoline-4-carboxylate anions. A pair of 2-phenylquinoline-4-carboxylate anions bridge two Mn cations, forming the dinuclear molecule. An intramoleculr O—H...O hydrogen bond occurs. Intermolecular O—H...O and O—H...N hydrogen bonds are present in the crystal structure.
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