SYNTHESIS AND CHARACTERIZATION OF C-HEXYL CALIX[4]RESORCINARENA FROM RESORCINOL-HEPTANAL CONDENSATION
| Autor: | Desi Suci Handayani, Zainal Arifin Almaqqomul Amin, Triana Kusumaningsih, Abu Masykur |
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| Jazyk: | English<br />Indonesian |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Alchemy, Vol 10, Iss 1, Pp 49-53 (2016) |
| Druh dokumentu: | article |
| ISSN: | 1412-4092 2443-4183 |
| DOI: | 10.20961/alchemy.v10i1.730 |
| Popis: | Synthesis of C-hexyl calix[4]resorcinarene through condensation reaction between resorcinol and heptanal with HCl catalyst has been investigated. Synthesis conducted by the ratio of resorcinol: heptanal (1:1) using reflux for 6 hours in ethanol. Structural analysis of the product was done by FTIR and 1 H-NMR spectroscopy, while the characterization was done by determining melting point. The product was golden brown powder with a yield 99.43% and melting point more than 300 °C. Structural analysis with FTIR and 1 HNMR known vibration and signals characteristic of calix[4]resorcinarena group, the vibrations of the CH bridge. Vibration of CH bridge appearance at wave number 1445 cm-1 and 1456 cm-1, while signal of CH bridge appearance at chemical shifts from 4.17 to 4.21 ppm. |
| Databáze: | Directory of Open Access Journals |
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