Study on Synthesis and Properties of K2SiF6: Mn4+ Phosphor

Autor: HE Qing-yang, ZHU Yue-hua, ZHUO Ning-ze, WANG Hai-bo
Jazyk: čínština
Rok vydání: 2018
Předmět:
Zdroj: Cailiao gongcheng, Vol 46, Iss 8, Pp 51-56 (2018)
Druh dokumentu: article
ISSN: 1001-4381
DOI: 10.11868/j.issn.1001-4381.2016.001243
Popis: K2SiF6:Mn4+ phosphor was prepared by wet chemical etching, and the effect of the raw material molar ratio of K/Mn of different materials and different reaction time on the structure and properties of phosphor was studied,the surface of K2SiF6:Mn4+ was coated with SiO2 to improve the thermal stability of K2SiF6:Mn4+ phosphor by sol-gel method. The structure, morphology, excitation spectrum and emission spectrum of phosphor powder were characterized by X-ray diffraction, scanning electron microscope and fluorescence spectrometer. The results show that the change of K/Mn ratio does not change the crystal structure of K2SiF6:Mn4+, the sample has cubic structure. At 460nm excitation, the strongest narrowband emission peak is located at 630nm (2Eg → 4A2). The crystal structure of K2SiF6:Mn4+ phosphor coated with SiO2 has not been changed. The results show that the thermal stability of the K2SiF6:Mn4+ phosphor coated with SiO2 is improved.
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